1-[(3-Benzyloxy-2-nitrophenoxy)methyl]benzene
نویسندگان
چکیده
منابع مشابه
Synthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate.
Triethylamine (Et3N) mediates esterification reactions between the title reagent (1) and carboxylic acids. Alcohols, phenols, amides, and other sensitive functionality are not affected; a dual role for Et3N as a promoter and a scavenger is postulated. Benzyl esters are obtained from substrates including amino acid and sugar derivatives.
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In the title compound, C(20)H(19)NO(5), the dihydro-furan ring is almost planar [maximum deviation of 0.021 (2)°] and makes dihedral angles of 28.1 (7) and 54.5 (5)° with the benzyl and phenyl-amino rings, respectively. The mol-ecular packing is stabilized by intra-molecular N-H⋯O hydrogen bonds and inter-molecular C-H⋯O inter-actions.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812029194